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Literature summary extracted from

  • Rabe, P.; Dickschat, J.S.
    The EIMS fragmentation mechanisms of the sesquiterpenes corvol ethers A and B, epi-cubebol and isodauc-8-en-11-ol (2016), Beilstein J. Org. Chem., 12, 1380-1394 .
    View publication on PubMedView publication on EuropePMC

Application

EC Number Application Comment Organism
4.2.3.163 analysis PMAs and EIMS fragmentation mechanisms for the fragment ions of reaction product Kitasatospora setae
4.2.3.171 analysis PMAs and EIMS fragmentation mechanisms for the fragment ions of reaction product Kitasatospora setae

Cloned(Commentary)

EC Number Cloned (Comment) Organism
4.2.3.170 recombinant enzyme expression in Escherichia coli strain BL21 Streptosporangium roseum

Natural Substrates/ Products (Substrates)

EC Number Natural Substrates Organism Comment (Nat. Sub.) Natural Products Comment (Nat. Pro.) Rev. Reac.
4.2.3.163 (2E,6E)-farnesyl diphosphate + H2O Kitasatospora setae
-
 (+)-corvol ether B + diphosphate
-
 ?
4.2.3.163 (2E,6E)-farnesyl diphosphate + H2O Kitasatospora setae DSM 43861
-
 (+)-corvol ether B + diphosphate
-
 ?
4.2.3.170 (2E,6E)-farnesyl diphosphate + H2O Streptosporangium roseum
-
 4-epi-cubebol + diphosphate
-
 ?
4.2.3.170 (2E,6E)-farnesyl diphosphate + H2O Streptosporangium roseum DSM 43021
-
 4-epi-cubebol + diphosphate
-
 ?
4.2.3.171 (2E,6E)-farnesyl diphosphate + H2O Kitasatospora setae
-
 (+)-corvol ether A + diphosphate
-
 ?
4.2.3.171 (2E,6E)-farnesyl diphosphate + H2O Kitasatospora setae DSM 43861
-
 (+)-corvol ether A + diphosphate
-
 ?

Organism

EC Number Organism UniProt Comment Textmining
4.2.3.163 Kitasatospora setae
-
-
-
4.2.3.163 Kitasatospora setae DSM 43861
-
-
-
4.2.3.170 Streptosporangium roseum
-
-
-
4.2.3.170 Streptosporangium roseum DSM 43021
-
-
-
4.2.3.171 Kitasatospora setae
-
-
-
4.2.3.171 Kitasatospora setae DSM 43861
-
-
-

Substrates and Products (Substrate)

EC Number Substrates Comment Substrates Organism Products Comment (Products) Rev. Reac.
4.2.3.163 (2E,6E)-farnesyl diphosphate + H2O
-
 Kitasatospora setae (+)-corvol ether B + diphosphate
-
 ?
4.2.3.163 (2E,6E)-farnesyl diphosphate + H2O
-
 Kitasatospora setae DSM 43861 (+)-corvol ether B + diphosphate
-
 ?
4.2.3.170 (2E,6E)-farnesyl diphosphate + H2O
-
 Streptosporangium roseum 4-epi-cubebol + diphosphate
-
 ?
4.2.3.170 (2E,6E)-farnesyl diphosphate + H2O
-
 Streptosporangium roseum DSM 43021 4-epi-cubebol + diphosphate
-
 ?
4.2.3.170 additional information product determination and identification by EIMS fragmentation and MS spectrometry, overview. Analysis of different cyclization products from farnesyl diphosphate by action of different enzymes Streptosporangium roseum ?
-
 ?
4.2.3.170 additional information product determination and identification by EIMS fragmentation and MS spectrometry, overview. Analysis of different cyclization products from farnesyl diphosphate by action of different enzymes Streptosporangium roseum DSM 43021 ?
-
 ?
4.2.3.171 (2E,6E)-farnesyl diphosphate + H2O
-
 Kitasatospora setae (+)-corvol ether A + diphosphate
-
 ?
4.2.3.171 (2E,6E)-farnesyl diphosphate + H2O
-
 Kitasatospora setae DSM 43861 (+)-corvol ether A + diphosphate
-
 ?

Synonyms

EC Number Synonyms Comment Organism
4.2.3.170 epi-cubebol synthase
-
 Streptosporangium roseum